Ethyl acetate effect on the human body. Butyl acetate and ethyl acetate: properties and applications. See what "Ethyl ester of acetic acid" is in other dictionaries

Ethyl acetate - ester acetic acid and ethyl alcohol and its chemical properties are typical of esters.

Ethyl acetate is the most widely used solvent due to its low toxicity and low cost, as well as its acceptable odor.

Ethyl acetate is soluble in water, ethanol, diethyl ether, chloroform, benzene and other solvents. Physico-chemical properties of larch wood and solutions of basic extractives.

Ethyl acetate CH3C(O)OC2H5, ethyl acetic acid is a colorless, transparent, flammable liquid with a pleasant odor. Ethyl acetate has relatively low toxicity. Ethyl acetate is a by-product of this process.

One of the most common esters is ethyl acetate, ethyl acetate. Its scent is reminiscent of pears, but a little sharper and not quite fruity. First, excess acetaldehyde, water and ethyl acetate (solvent) are separated from the oxidate, after which the residue is separated into acetic acid, acetic anhydride and catalyst in another column.

Ethyl acetate and water are also further separated and the former is again used as a diluent and solvent. A major accident occurred at the ethyl acetate-acetone condensation unit in the presence of sodium metal. However, it should be borne in mind that the difference in costs is due solely to the fact that expensive ethyl acetate is used at the extraction stage of non-sulfonated compounds.

Ethyl acetate is a mobile organic liquid with a pungent odor of ether. The full Russian name is ethyl ester of acetic acid, rational formula CH3COOC2H5, registration number CAS 141-78-6.

Ethyl acetate is considered a low-toxic reagent, but upon contact with human skin, ethyl acetate can cause allergic dermatitis; Ether vapors irritate the organs of vision and breathing.

Ethyl acetate grade A technical is a volatile, colorless liquid with a fruity odor.

Technical ethyl acetate is stored in warehouses or in specially equipped metal containers in compliance with the rules for storing flammable substances. The maximum permissible concentration in the air of the working area is 200 mg/m3. Technical ethyl acetate is a flammable liquid and, when mixed with air, forms an explosive mixture of category PA, group T2 according to GOST 12.1.011.

If the groups R and R’ in a simple ether are the same, then it is called symmetrical, if they are different, it is called asymmetrical. Dioxane, cyclic ether (CH2CH2O)2 is similar in chemical properties to ordinary ethers, but unlike them, it is unlimitedly miscible with water and most organic solvents.

Chemical properties and preparation

The physicochemical properties of the most common esters are given in the table. A process for producing ethyl acetate based on methyl alcohol has been developed abroad. Ethyl acetate, like acetone, dissolves most polymers.

The addition of 15-20% ethyl alcohol increases the dissolving ability of ethyl acetate in relation to cellulose ethers, especially cellulose acetate.

Amyl acetate is widely used as a varnish solvent because it evaporates more slowly than ethyl acetate.

This is an indicator of the low polarity of dialkyl ethers and the absence (unlike alcohols) of prerequisites for the formation of hydrogen bonds.

Esters of lower carboxylic acids and alcohols are volatile, water-insoluble liquids. Esters of higher fatty acids and alcohols are waxy substances, odorless, and insoluble in water.

Fats are soluble in organic solvents and insoluble in water.

You can buy ethyl acetate wholesale from us at an affordable price. Ethyl acetate has a quality certificate. The presence of our own warehouses and vehicle fleet ensures efficiency in fulfilling orders and delivery of ethyl acetate throughout Ukraine. The price of ethyl acetate also depends on the volume of purchases. When purchasing ethyl acetate in bulk, our managers will provide you with personal discounts.

Ethyl acetate is often used for the extraction of organic compounds from aqueous solutions, as well as for column and thin layer chromatography. Ethyl acetate is used as a reagent and reaction medium in chemical and pharmaceutical production.

Areas of application of ethyl acetate

Ethyl acetate is registered as food additives E1504, which is used as a component of fruit essences that are added to various liqueurs, drinks and confectionery products.

If you need to buy ethyl acetate in bulk, contact System Optimum.

You can quickly resolve the issue of the price of ethyl acetate, as well as terms of payment and delivery in Ukraine, with the company’s specialists by phone or via e-mail.

Insects after killing in its vapors are much softer and more pliable in dissection than after killing in chloroform vapors. Limited soluble in water (up to 12% by weight). Easily hydrolyzes to ethanol and acetic acid in an alkaline environment. In an acidic environment it can be transesterified.

Esterification of acetic acid with ethyl alcohol in the presence of a catalyst (sulfuric acid, para-toluenesulfonic acid or ion exchange resins) at a temperature of 110-115°C. The ratio of acetic acid and alcohol in the process is 1:1.1. The cost of acetic acid is slightly higher than the cost of ethanol, so maximum acid conversion is achieved.

5 and 10 mg/l (Meleshchenko). The gases leaving the furnace (where oxidation occurs) are freed from acetaldehyde by washing with water and are discharged from the installation.

The explosion was caused by insufficient cooling of the apparatus before loading sodium and accidental entry of moisture into the reactor. In the future, the process of co-production of synthetic fatty acids and sodium alkyl sulfates may be of practical interest.

In relation to the process of direct hydrogenation of acids, the cost of 1 ton of sodium alkyl sulfates in this case is 106.4%.

Ethyl acetate grade A GOST 8981-78

Solubility in water - 12% by weight; miscible with methanol, ethanol, diethyl ether, benzene, carbon trichloride, chloroform. Storage conditions: closed warehouse with low humidity, cool and fireproof. The container must be undamaged and tightly closed; Do not store containers with ether near heat sources or in bright sunlight.

It is widely used in the production of various substances and household items. Can be mixed with water and organic solvents in any proportions.

In terms of the degree of impact on the human body, technical ethyl acetate is classified as a low-hazard substance (hazard class 4). You can obtain your login and password from the administrator. Ethyl alcohol is produced by fermentation of food raw materials. From 1930-1950s.

Methods have been developed for producing synthetic alcohol by hydration of ethylene and hydrogenation of acetaldehyde.

Ethyl acetate vapors irritate the mucous membranes of the eyes and respiratory tract. When applied to the skin it causes dermatitis and eczema. Ethyl acetate is always available at the warehouses of the State of Emergency System Optimum. A mixture consisting of acetaldehyde, ethyl acetate and water is separated in a special column from acetaldehyde, which is also returned for oxidation.

ethyl acetate formula, ethyl acetate
(ethyl ester of acetic acid) CH3-COO-CH2-CH3 is a colorless volatile liquid with a pungent odor.

  • 1 Receipt
  • 2 Physical properties
  • 3 Application
    • 3.1 Laboratory use
  • 4 Cleaning and drying
  • 5 Security
  • 6 Notes

Receipt

Ethyl acetate is formed by the direct reaction of ethanol with acetic acid:

C H 3 C O O H + C 2 H 5 O H → C H 3 C O O C 2 H 5 + H 2 O (displaystyle (mathsf (CH_(3)COOH+C_(2)H_(5)OH
ightarrow CH_(3)COOC_(2)H_(5)+H_(2)O)))

A laboratory method for producing ethyl acetate involves acetylation of ethyl alcohol with acetyl chloride or acetic anhydride:

C H 3 C O C l + C 2 H 5 O H → C H 3 C O O C 2 H 5 + H C l (displaystyle (mathsf (CH_(3)COCl+C_(2)H_(5)OH
ightarrow CH_(3)COOC_(2)H_(5)+HCl)))

Industrial methods for the synthesis of ethyl acetate include:

  1. Distillation of a mixture of ethyl alcohol, acetic and sulfuric acids.
  2. Treatment of ethyl alcohol with ketene.
  3. According to the Tishchenko reaction from acetaldehyde at 0-5 °C in the presence of catalytic quantities of aluminum alkoxide:

2 C H 3 C H O → C H 3 C O O C 2 H 5 (displaystyle (mathsf (2CH_(3)CHO
ightarrow CH_(3)COOC_(2)H_(5))))

Physical properties

Colorless mobile liquid with a pungent odor of ether. Molar mass 88.11 g/mol, melting point −83.6 °C, boiling point 77.1 °C, density 0.9001 g/cm³, n204 1.3724.

Dissolves in water 12% (by weight), in ethanol, diethyl ether, benzene, chloroform; forms double azeotropic mixtures with water (bp.

Application

Ethyl acetate is widely used as a solvent due to its low cost and low toxicity, as well as its acceptable odor.

In particular, as a solvent for cellulose nitrates, cellulose acetate, fats, waxes, for cleaning printed circuit boards, mixed with alcohol - a solvent in the production of artificial leather.

Annual world production in 1986 was 450-500 thousand tons. World production of ethyl acetate in 2014 is about 3.5 million tons per year.

One of the most popular poisons used in entomological stains to kill insects. Insects after killing in its vapors are much softer and more pliable in dissection than after killing in chloroform vapors.

Used as a component of fruit essences. Registered as a dietary supplement E1504.

Laboratory Application

Ethyl acetate is often used for extraction and for column and thin layer chromatography. Rarely used as a reaction solvent due to its tendency to hydrolysis and transesterification.

Used to produce acetoacetic ester:

2 C H 3 C O O C 2 H 5 → C H 3 C O C H 2 C O O C 2 H 5 (displaystyle (mathsf (2CH_(3)COOC_(2)H_(5)
ightarrow CH_(3)COCH_(2)COOC_(2)H_(5))))

Cleaning and drying

Commercial ethyl acetate usually contains water, alcohol and acetic acid. To remove these impurities, it is washed with an equal volume of 5% sodium carbonate, dried with calcium chloride and distilled.

For higher water requirements, phosphorus anhydride is added several times (in portions), filtered and distilled, protecting from moisture.

Using a 4A molecular sieve, the water content of ethyl acetate can be reduced to 0.003%.

Safety

The LD50 for rats is 11.6 g/kg, indicating low toxicity. Ethyl acetate vapors irritate the mucous membranes of the eyes and respiratory tract and cause dermatitis and eczema when exposed to the skin. The maximum permissible concentration in the air of the working area is 200 mg/m³. The maximum permissible concentration in the atmospheric air of populated areas is 0.1 mg/m³.

Flash point - 2 °C, auto-ignition temperature - 400 °C, concentration limits of vapor explosion in air 2.1-16.8% (by volume).

Safety during transportation. In accordance with ADR (ADR), hazard class 3, UN code 1253.

Notes

  1. Chemical Encyclopedia, Moscow 1998, p. 494
  2. Organicum. Volume 2. Moscow, Mir, 1992, p. 180
  3. Maximum permissible concentrations (MPC) of pollutants in the atmospheric air of populated areas

ethyl acetate formula, ethyl acetate, ethyl acetate formula, ethyl acetate

Ethyl Acetate Information About


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Where is ethyl acetate used?

is an ethyl ester of ethanoic acid in the form of a flammable, colorless, volatile liquid substance with a pungent odor of fruit. There are no mechanical impurities. It is a moderately polar solvent product with the properties of esters.

Can be dissolved in methyl carbinol, ethyl ether, benzene, methyl trichloride, methylbenzene and some other organic solvents. As for water, the dissolution in it is weaker.

It itself has a dissolving effect on cellulose ethers, oil-based resin varnishes, fats and waxes.

Molar mass – 88.11 g/mol, density – 0.902 g/cm³. Thermal properties: melting temperature – -83 °C, boiling temperature – 77 °C. Formula: C4H8O2.

Receipt in industry scale occurs during the reaction of ethanol and acetic acid. It is also possible to treat ethanol with carbomethylene or synthesize it from acetaldehyde in the presence of an aluminum alkoxide catalyst.

Applications of ethyl acetate

the role of this substance is dissolving (this takes up a third of all produced ethanoic acid ester). It is preferred among other solvents due to its low price, low toxicity and quite tolerable odor.

It is used to dissolve nitro- and cellulose acetate, waxes and fats, nitroglyphthalic, perchlorovinyl, epoxy, polyester, silicone varnishes, paints, enamels, and also clean printed circuit boards.

Thus, it is used in the production of LC materials, adhesive compositions and inks for printing equipment. When packaging goods using all kinds of flexible packaging materials, it is taken for dissolution during the stencil application of inscriptions and drawings.

Together with alcohol, ethyl acetate as a solvent is used, among other things, in the manufacture of artificial leather.

It is also the most popular pesticide. It is part of entomological stains (the task is to kill insects). Compared to the same chloroform, which is used for a similar purpose, ethyl acetate softens the object of influence more and makes it more pliable in preparation.

This substance is used due to its low toxicity and as a component of fruit essences. This is a well-known food additive E1504. It is added to cooling drinks, liqueurs and various confectionery products. It is used to extract caffeine from coffee.

In laboratory practice, it is used in extraction to pull out the organ. substances from aqueous solutions and chromatography (column and thin layer). Sometimes acts as a solvent in some chemicals. reactions. The rarity of such use is explained by the tendency to solvolysis with water and transesterification.

Pharmacists use it as a reaction medium for the manufacture of a number of drugs: methoxazole, hydrocortisone, rifampicin, etc.

Ethyl acetate is a participant in the synthesis of acetoacetic acid ethyl ester.

When creating explosives, it acts as a gelatinizer. In the electronics industry, when creating aluminum foil and thin sheets of aluminum - as a cleaner and disinfectant. It is also used in the creation of photographs, films, cellophane, and all kinds of technical materials. rubber products.

Ethyl acetate in industry

Or ethanoic acid ester, is widely used in various industries. industries, performing a large list of tasks:

– in paint and varnish, glue, pulp production and the production of artificial leather, ink for typewriters acts as a solvent. The solvent also acts when applying ink drawings and inscriptions to packaging materials;

– in the pharmaceutical industry it serves as a reagent and reaction medium in the manufacture of drugs;

– in the creation of aluminum foil and thin sheets of aluminum – with a degreaser;

– in the electronics industry it is also used for degreasing and also for cleaning;

– in the food industry it is a popular extractant (for example, it helps extract caffeine from coffee). In addition, it is used in the creation of cooling drinks, liqueurs, confectionery and fruit essences;

– in the production of explosives – gelatinizer;

– in the cosmetics industry it is introduced into manicure products, in particular for removing varnish from nails.

This breadth of application is due to the relative low cost, low toxicity and efficiency in each of the above processes.

Due to its high efficiency and functionalism, taking into account its low toxicity, ethyl acetate has become so widely used.

Author: Chemical Encyclopedia N.S. Zefirov

ETHYL ACETATE(ethyl acetate) CH 3 COOC 2 H 5 ; molecular weight 88.11; colorless liquid with a pleasant odor; melting point -84 °C, boiling point 77.1 °C; 0.9001; 1.3724; t crit 250.4 o C, P crit 3.78 MPa; 0.455 mPa x s (20 °C); 6.03 x 10 -30 Cl x m; 34.75 J/mol, 10.481 J/mol; -2254.98 kJ/mol, -463.8 kJ/mol; 6.053; miscible with ethanol, diethyl ether, benzene, CHCl 3 ; solubility (% by weight): in water 12, water in ETHYL ACETATE 9.7. ETHYL ACETATE forms double azeotropic mixtures with water (boiling point 70.4 °C, water content 8.2% by weight), ethanol (71.8; 30.8), methanol (62.25; 44.0), isopropanol ( 75.3; 21.0), CCl 4 (74.7; 57), cyclohexane (72.8; 54.0) and a ternary azeotropic mixture ETHYL ACETATE: water: ethanol (boiling point 70.3 ° C, content, respectively, 83 .2, 7.8 and 9% by weight).
ETHYL ACETATE has all the properties of esters.
In industry, ETHYL ACETATE is obtained: 1) according to Tishchenko’s reaction from acetaldehyde at 0-5 °C in the presence of catalytic quantities of Al alcoholate; acetaldehyde conversion 98%, selectivity 97-98%; 2) esterification of CH 3 COOH with ethanol at 110-115 °C in the presence of H 2 SO 4, acid to alcohol ratio (1:1.1), conversion degree more than 95%; 3) interaction of CH 3 COOH with ethylene at a temperature of 150 °C and a pressure of 7.7 MPa in the presence of H 2 SO 4 at a ratio of CH 3 COOH: ethylene 1: 3.89.
Laboratory methods of preparation: interaction of C 2 H 5 OH with CH 3 COCl, ketene or (CH 3 CO) 2 O, or reaction of CO with CH 3 OH and ethylene.
ETHYL ACETATE is a solvent for nitrocellulose, cellulose acetate, resin oil varnishes, fats, waxes, mixed with alcohol - a solvent in the production of arts. skin. It is used as an extractant, an organic compound from aqueous solutions, a gelatinizing agent in production explosives, a component of fruit essences.
ETHYL ACETATE vapors irritate the mucous membranes of the eyes and breath. ways, when exposed to the skin, they cause dermatitis and eczema. The maximum permissible concentration in the air of the working area is 200 mg/m3.
Flash point 2 °C, ignition temperature below O °C, i.e. self-ignition. 400 °C, vapor emission factor in air 2.1-16.8% (by volume), ignition temperature limits 1-31 °C.
World production volume of ETHYL ACETATE is 0.45-0.5 million tons per year (1986), incl. in Japan 0.11, Germany 0.08, USA 0.08.

Literature: Reed R., Prausnitz J., Sherwood T., Properties of Gases and Liquids, trans. from English, L., 1982; Kirk-Othmer encyclopedia, 3 ed., v. 21, N.Y., 1983, p. 382-83.

3. P. Prisyazhnyuk.

Chemical encyclopedia. Volume 5 >>

is an ethyl ester of ethanoic acid in the form of a flammable, colorless, volatile liquid substance with a pungent odor of fruit. There are no mechanical impurities. It is a moderately polar solvent product with the properties of esters. Can be dissolved in methyl carbinol, ethyl ether, benzene, methyl trichloride, methylbenzene and some other organic solvents. As for water, the dissolution in it is weaker. It itself has a dissolving effect on cellulose ethers, oil-based resin varnishes, fats and waxes.

Molar mass – 88.11 g/mol, density – 0.902 g/cm³. Thermal properties: melting temperature – -83 °C, boiling temperature – 77 °C. Formula: C 4 H 8 O 2.

Receipt in industry scale occurs during the reaction of ethanol and acetic acid. It is also possible to treat ethanol with carbomethylene or synthesize it from acetaldehyde in the presence of an aluminum alkoxide catalyst.

Applications of ethyl acetate

The main role of this substance is dissolving (this takes up a third of all ethanoic acid ethyl ester produced). It is preferred among other solvents due to its low price, low toxicity and quite tolerable odor. It is used to dissolve nitro- and cellulose acetate, waxes and fats, nitroglyphthalic, perchlorovinyl, epoxy, polyester, silicone varnishes, paints, enamels, and also clean printed circuit boards. Thus, it is used in the production of LC materials, adhesive compositions and inks for printing equipment. When packaging goods using all kinds of flexible packaging materials, it is taken for dissolution during the stencil application of inscriptions and drawings. Together with alcohol, ethyl acetate as a solvent is used, among other things, in the manufacture of artificial leather.

It is also the most popular pesticide. It is part of entomological stains (the task is to kill insects). Compared to the same chloroform, which is used for a similar purpose, ethyl acetate softens the object of influence more and makes it more pliable in preparation.

This substance is used due to its low toxicity and as a component of fruit essences. This is a well-known food additive E1504. It is added to cooling drinks, liqueurs and various confectionery products. It is used to extract caffeine from coffee.

In laboratory practice, it is used in extraction to pull out the organ. substances from aqueous solutions and chromatography (column and thin layer). Sometimes acts as a solvent in some chemicals. reactions. The rarity of such use is explained by the tendency to solvolysis with water and transesterification.

Pharmacists use it as a reaction medium for the manufacture of a number of drugs: methoxazole, hydrocortisone, rifampicin, etc.

Ethyl acetate is a participant in the synthesis of acetoacetic acid ethyl ester.

When creating explosives, it acts as a gelatinizer. In the electronics industry, when creating aluminum foil and thin sheets of aluminum - as a cleaner and disinfectant. It is also used in the creation of photographs, films, cellophane, and all kinds of technical materials. rubber products .

Ethyl acetate in industry

Ethyl acetate, or ethanoic acid ester, is widely used in various industries. industries, performing a large list of tasks:

– in paint and varnish, glue, pulp production and the production of artificial leather, ink for typewriters acts as a solvent. The solvent also acts when applying ink drawings and inscriptions to packaging materials;

– in the pharmaceutical industry it serves as a reagent and reaction medium in the manufacture of drugs;

– in the creation of aluminum foil and thin sheets of aluminum – with a degreaser;

– in the electronics industry it is also used for degreasing and also for cleaning;

– in the food industry it is a popular extractant (for example, it helps extract caffeine from coffee). In addition, it is used in the creation of cooling drinks, liqueurs, confectionery and fruit essences;

– in the production of explosives – gelatinizer;

– in the cosmetics industry it is introduced into manicure products, in particular for removing varnish from nails.

This breadth of application is due to the relative low cost, low toxicity and efficiency in each of the above processes.

Due to its high efficiency and functionalism, taking into account its low toxicity, ethyl acetate has become so widely used.

Sale of solvents, the assortment includes simple solvents: Acetone, White Spirit, Ethyl Acetate, etc. The Olio company also sells mixed solvents using its own technologies, analogues of imported products, and can also produce a product according to your recipe.
The most popular products are always in stock; custom orders require several days for production.
Quality guarantee, reasonable prices, certificates and passports for solvents available.

Ethyl acetate (ethyl acetate)

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  • Kilogram - 94 rub.
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  • Canister, 5 l - 441 rub.
  • Canister, 10 l - 869 rub.
  • Canister, 20 l - 1733 RUR

Discounts are possible depending on order volume.

Ethers - organic matter, formed by the interaction of alcohols and acids. Alcohol + acid = ether + water. Ethyl acetate is the result of the esterification of ethyl alcohol and acetic acid. All esters are practically insoluble in water, but interact with water by reacting (hydrolysis of esters is the reverse process of esterification). Ethyl acetate(ethyl acetic acid) is a colorless liquid with a characteristic odor. The literature indicates that ethyl acetate and butyl acetate have a fruity odor. Maybe. But most people who work directly with ethyl acetate are more inclined to think that its smell is reminiscent of acetone, with a slightly sweeter tint. Ethyl acetate is a classic representative of esters (group No. 3 in the classification of solvents for the paint and varnish industry).

As a result, an equilibrium system is formed - on one side there is ether and water, on the other there is alcohol and acid. Although ethyl acetate does not contain water, due to storage conditions (condensation in containers) or in the composition of mixed solvents where water may be present (this is solvent R-646, R-645, R-649, R-650, i.e. practically All solvents that contain alcohols) ethyl acetate, interacting with water, breaks down into its original components - acetic acid and ethyl alcohol. This is why acidity increases over time in solvents containing esters.

Moreover ethyl acetate It mixes better with water than butyl acetate and interacts with it more actively. In the early 90s, some talented chemistry students used ethyl acetate to extract ethyl alcohol. If anyone remembers, it was difficult to find alcohol in stores, and there was a lot of cheap ethyl acetate. Ethyl acetate + water = ethyl alcohol + acid. Neutralize the acid and distill the resulting mixture. Everyone had a good time.

Ethyl acetate mixes well with alcohols, acetone, toluene, orthoxylene, solvent, i.e. with all organic solvents. Dissolves cellulose ethers, oils, fats, chlorinated rubbers, vinyl polymers, carbinol resins, etc. Almost everything is the same as acetone, methyl acetate, butyl acetate. According to dissolving ability ethyl acetate close to acetone, but weaker than it, however, stronger than butyl acetate. Adding a small amount of alcohols enhances the dissolving ability of ethyl acetate.

Raw materials for production. To obtain ethyl acetate, technical acetic acid and ethyl alcohol are used.

Ethyl acetate consumption. Up to 90% of all ethyl acetate produced is consumed by the paint and varnish industry (enamels, paints, varnishes, primers, adhesives, solvents). The remaining volume is used in the production of artificial leather, rubber goods, plastics and pharmaceuticals, cosmetics and the food industry.

Manufacturers. OJSC Nevinnomyssk Azot, Nevinnomyssk, Stavropol Territory (among other things, a producer of acetic acid and butyl alcohol) is part of OJSC Eurochem, OJSC Ashinsky Chemical Plant, Chelyabinsk region, OJSC Karbokhim, Perm, OJSC Amzinsky Timber Plant. Amzya Bashkiria, FKP "Plant named after Ya.M. Sverdlov" Dzerzhinsk.

Ethyl acetate GOST 8981-78

Indicator name Standard according to GOST for grade "A"
Top grade First grade
1. Appearance Transparent liquid without mechanical impurities
2. Chromaticity, Hazen units, no more 5 10
3. Density at a temperature of 20°C, g/cm 0,898-0,900 0,897-0,900
4. Mass fraction of the main substance % not less than 99,0 98,0
5. Mass fraction of acids in terms of acetic acid, %, no more 0,004 0,008
6. Mass fraction of non-volatile residue, %, no more 0,001 0,003
7. Temperature limits for distillation at a pressure of 101.3 kPa (760 mm Hg): 95% (by volume) of the product must be distilled within the temperature range, C° 75 ― 78 74 ― 79
8. Mass fraction of water, %, no more 0,1 0,2
9. Mass fraction of aldehydes in terms of acetaldehyde, %, no more no more than 0.05% Not standardized
10. Relative volatility (based on ethyl ether) 2 ― 3 2 ― 3

You can buy ethyl acetate (ethyl ester of acetic acid) in our warehouse, near Podolsk and Klimovsk

Ethyl acetate (ethyl acetate)

Ethyl acetate(ethyl ester of acetic acid) is a colorless liquid with a characteristic odor. The literature indicates that ethyl acetate and butyl acetate have a fruity odor. Maybe. But most people who work directly with ethyl acetate are more inclined to think that its smell is reminiscent of acetone, with a slightly sweeter tint. Ethyl acetate is a classic representative of esters (group No. 3 in the classification of solvents for the paint and varnish industry. See the “Products” section).

Ethers- organic substances formed by the interaction of alcohols and acids. Alcohol + acid = ether + water. (See Butyl Acetate section for more details). Ethyl acetate is the result of the esterification of ethyl alcohol and acetic acid. All esters are practically insoluble in water, but interact with water by reacting (hydrolysis of esters is the reverse process of esterification).

As a result, an equilibrium system is formed - on one side there is ether and water, on the other there is alcohol and acid. Although ethyl acetate does not contain water, due to storage conditions (condensation in containers) or in the composition of mixed solvents where water may be present (this is solvent R-646, R-645, R-649, R-650, i.e. practically All solvents that contain alcohols) ethyl acetate, interacting with water, breaks down into its original components - acetic acid and ethyl alcohol. This is why acidity increases over time in solvents containing esters.

Moreover ethyl acetate It mixes better with water than butyl acetate and interacts with it more actively. In the early 90s, some talented chemistry students used ethyl acetate to extract ethyl alcohol. If anyone remembers, it was difficult to find alcohol in stores, and there was a lot of cheap ethyl acetate. Ethyl acetate + water = ethyl alcohol + acid. Neutralize the acid and distill the resulting mixture. Everyone had a good time.

Ethyl acetate mixes well with alcohols, acetone, toluene, orthoxylene, solvent, i.e. with all organic solvents. Dissolves cellulose ethers, oils, fats, chlorinated rubbers, vinyl polymers, carbinol resins, etc. Almost everything is the same as acetone, methyl acetate, butyl acetate. According to dissolving ability ethyl acetate close to acetone, but weaker than it, however, stronger than butyl acetate. Adding a small amount of alcohols enhances the dissolving ability of ethyl acetate.

Raw materials for production. To obtain ethyl acetate, technical acetic acid and ethyl alcohol are used.

Ethyl acetate consumption. Up to 90% of all ethyl acetate produced is consumed by the paint and varnish industry (enamels, paints, varnishes, primers, adhesives, solvents). The remaining volume is used in the production of artificial leather, rubber goods, plastics and pharmaceuticals, cosmetics and the food industry.

Manufacturers. OJSC Nevinnomyssk Azot, Nevinnomyssk, Stavropol Territory (among other things, a producer of acetic acid and butyl alcohol) is part of OJSC Eurochem, OJSC Ashinsky Chemical Plant, Chelyabinsk region, OJSC Karbokhim, Perm, OJSC Amzinsky Timber Plant. Amzya Bashkiria, FKP "Plant named after Ya.M. Sverdlov" Dzerzhinsk.

Ethyl acetate GOST 8981-78

Indicator name Standard according to GOST for grade "A"
Top grade First grade
1. Appearance Transparent liquid without mechanical impurities
2. Chromaticity, Hazen units, no more 5 10
3. Density at a temperature of 20°C, g/cm 0,898-0,900 0,897-0,900
4. Mass fraction of the main substance % not less than 99,0 98,0
5. Mass fraction of acids in terms of acetic acid, %, no more 0,004 0,008
6. Mass fraction of non-volatile residue, %, no more 0,001 0,003
7. Temperature limits for distillation at a pressure of 101.3 kPa (760 mm Hg): 95% (by volume) of the product must be distilled within the temperature range, C° 75 - 78 74 - 79
8. Mass fraction of water, %, no more 0,1 0,2
9. Mass fraction of aldehydes in terms of acetaldehyde, %, no more no more than 0.05% Not standardized
10. Relative volatility (based on ethyl ether) 2 - 3 2 - 3

You can buy ethyl acetate (ethyl ester of acetic acid) in our warehouse, near Podolsk and Klimovsk